Home › Top 4 Gas Stations in Llano, Texas Find best Gas Stations in Llano, Texas, with all necessary contact information, including addresses, phone numbers, working hours, map locations, and website links. Valero - Llano (TX 78643) US, Llano, TX 78643307 W Young St Chevron Llano US, Llano, TX 78643403 W Young St Sunoco - Llano (TX 78643) US, Llano, TX 78643200 State Hwy 71 Mobil - Llano (TX 78643) US, Llano, TX 786431501 Ford St